FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170

FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

ASSESSMENT OF HEAVY METALS IN EDIBLE CLAYS SOLD IN ONITSHA METROPOLIS OF ANAMBRA STATE, NIGERIA
Pages: 610-614
H. I. Kelle1, E. O. Otokpa, V. U. Oguezi and F. C. Ibekwe


keywords: Cadmium, edible clay, heavy metals, mercury, permissible limit

Abstract

This study was undertaken to determine and compare the level of heavy metals- zinc, lead, cadmium, copper, mercury and cobalt in two species of edible clay (Nzu and Ulo) sold in four major markets namely; Ochanja, Ose, Relief and Okpoko, in Onitsha metropolis of Anambra state, Nigeria. Heavy metals in the edible clay samples were analysed by atomic absorption spectrophotometry. Mean concentrations were computed from three replicate measurements. Data from the markets were compared by One-Way ANOVA while data between the clay types were analyzed by independent t-test. The result of the study indicate that mean concentrations (ppm) of Zn, Pb, Cd, Cu, and Co showed no significant difference [(P =.981, .479, .335, .333 and .613) for Zn, Pb, Cd, Cu, and Co respectively] among markets. The mean concentration (ppm) of Hg (2.335±0.276) in Ochanja market however, differ significantly (P =.045) from those of the other markets, 0.621±0.244, 0.796±0.280 and 0.251±0.190 for Ose, Relief and Okpoko, respectively. Statistically reliable differences were found for Zn (P =.000) and Co (P =.003) type 1(nzu) and 11 (ulo) mean concentrations. However, mean concentrations of Pb, Cd, Cu and Hg in type 1 and type 11 clays did not differ significantly [(P =.391, .288, .243, and .613) for Pb, Cd, Cu and Hg, respectively]. There were high concentrations of Hg in virtually all samples and Cd in few samples. The high levels of Cd and Hg in the analyzed edible clays make them unhealthy for human consumption. However, further research is required to validate the reliability of these findings.

References

Abrahams PW, Davies TC, Solomon AO, Trow AI & Wragg J 2013. Human geophagia, calabar chalk and undongo: mineral element nutritional implication. PLos One, 8(1): 1-5. Alexander MD, Wodwodt A & Akos Kiss FCS 2002. Geophagia: the history of earth eating. J. R. Soc. Med., 95(3): 143–146. Beer BO 1999. Bioaccumulation New Aspects and Developments. Springer Verlag, New York, pp. 85-90. Bisi-Johnson MA, Obi CL & Ekosse GE 2010. Microbiological and health related perspectives of geophagia: An overview. Afri. J. Biotech., 9(19): 5784–5791. Bonglaisin JN, Mbofung CMF & Lantum DN 2011. Intake of lead, cadmium and mercury in kaolin-eating: A quality assessment. J. Med. Sci., 11: 267-273. Christoph M, Theopistil L & Volker JD 2001. Determination of heavy metals in soils, sediments and geological materials by ICP-AES and ICP – MS. Mikrochimica Acta, 136(3-4): 123–128. Clay minerals research. Accessed 14 July 2017. Available: http://www.californiaearthminerals.com/science/clay-minerals-research.php?16. Dominy NY, Davoust E & Minekus M 2004. Adaptive function of soil consumption: An in vitro study modeling the human stomach and small intestine. J. Exp. Biol., 207(2): 319– 324. FAO 1983. Compilation of legal limits for hazardous substances in fish and fishery products. FAO Fishery Circular, 464: 5–100. FAO/WHO 1999. Expert Committee on food Additives, Summary and Conclusions, Proc. 53rd Joint FAO/WHO Expert Committee on Food Additive Meetings, Rome. FAO/WHO 2001. Food Additive, Codex Alimentarius Commission. Geophagy. Accessed 6 September, 2017. Available: http://en.wikipedia.org/wiki/Geophagy. Heu Z, Chen Z, Tsai C, Tsui C, Cheng S, Liu C & Lin H 2002. Digestion of total heavy metals in Sediments and soils. Water, Air and Soil Pollution, 14(1-4): 189-205. Mcloughlin IJ 1987. The picas. Br J. Hosp. Med., 37(4): 286–290. Mercury and Health. Accessed 10 September, 2017. Available: http://www.who.int/mediacentre/factsheets/fs3611. Nurnadi AA, Azrina A, Amin I, Mohd Yunus AS, MohdIzuan S & Effendi H 2013. Mineral contents of selected marine fish and shellfish from the west coast of peninsular Malaysia. Int. Food Res. J., 20(1): 431-437. Tuchschmid MP, Dietrich V, Richner P, Lienemann P, Desaules A, Kundig R & Vogler R 1995. Federal Office of Environment, Forests and Landscape (Buwal), Umweltmateria lien Nr. 32, Bern.

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